Abstract
In the title complex, [Cu(C7H5O3)2(C21H18N4O)2]·2H2O, the CuII atom is located on a centre of inversion and exists in a tetragonally distorted octahedral geometry with a CuN4O2 chromophore. The intramolecular O—H⋯O hydrogen bond is highly strained due to the molecular geometry and, as a result, is much shorter than expected. Intermolecular C—H⋯O and C—H⋯O interactions are also observed.
Highlights
In the title complex, [Cu(C7H5O3)2(C21H18N4O)2]Á2H2O, the CuII atom is located on a centre of inversion and exists in a tetragonally distorted octahedral geometry with a CuN4O2 chromophore
We are grateful to Jingye Pharmochemical Pilot Plant for financial assistance though project 8507040052
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BR2165)
Summary
In the title complex, [Cu(C7H5O3)2(C21H18N4O)2]Á2H2O, the CuII atom is located on a centre of inversion and exists in a tetragonally distorted octahedral geometry with a CuN4O2 chromophore. Related literature For general background to the coordination chemistry of 1,2,4-triazole derivatives, see: Koningsbruggen et al (1997); Garcia et al (1999); Klingele & Brooker (2003); Matsukizono et al (2008); Suksrichavalit et al (2009); Rubio et al (2011). Crystal data [Cu(C7H5O3)2(C21H18N4O)2]Á2H2O Mr = 1058.58 Triclinic, P1 a = 8.5933 (12) Ab = 10.6467 (15) Ac = 14.578 (2) A
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
