Bis(2-ethylhexyl)amine as an Effective Organocatalyst for the Racemic Reactions of α,β-Unsaturated Aldehydes Involving an Iminium Ion

Abstract

AbstractBis(2-ethylhexyl)amine is shown to be a suitable organocatalyst to prepare racemic compounds in the reactions of α,β-unsaturated aldehydes involving an iminium ion, whereas diphenylprolinol silyl ether is a well-known chiral organocatalyst for the asymmetric versions of the same reactions. The generality and limitations of bis(2-ethylhexyl)amine are disclosed.