Abstract
In the crystal structure of the title compound, (C7H10N)2[ZnBr4], the coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Zn atom. The Zn—Br bond lengths range from 2.400 (2) to 2.408 (3) Å and the Br—Zn—Br angles range from 108.14 (6) to 115.15 (15)°. In the crystal structure, the [ZnBr4]2− anion is connected to two cations through N—H⋯Br and H2C—H⋯Br hydrogen bonds, forming two-dimensional cation–anion–cation layers normal to the b axis. No significant Br⋯Br interactions [the shortest being 4.423 (4) Å] are observed in the structure.
Highlights
In the crystal structure of the title compound, (C7H10N)2[ZnBr4], the coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Zn atom
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
Basem Fares Alia* and Rawhi Al-Farb a Department of Chemistry, Al al-Bayt University, Mafraq 25113, Jordan, and bFaculty of Information Technology and Science, Al-Balqa’a Applied University, Salt, Jordan. Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.03 Å; R factor =. 0.088; wR factor = 0.177; data-to-parameter ratio = 20.2. In the crystal structure of the title compound, (C7H10N)2[ZnBr4], the coordination geometry of the anion is approximately tetrahedral and a twofold rotation axis passes through the Zn atom. The Zn—Br bond lengths range from 2.400 (2). The [ZnBr4]2 anion is connected to two cations through N—. H Br and H2C—H Br hydrogen bonds, forming twodimensional cation–anion–cation layers normal to the b axis. 4.423 (4) Å] are observed in the structure
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta crystallographica. Section E, Structure reports online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
