Abstract
The crystal structure of [Cu(NCO)(C10H8N2)2][C(CN)3] is formed by discrete [Cu(bipy)2(NCO)]+ cations and [C(CN)3]− anions (bipy is 2,2′-bipyridine). The coordination polyhedron of the CuII atom is a distorted trigonal bipyramid with a CuN5 chromophore.
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