Year-end Sale % OFF 
Abstract
In the title compound, [Zn(C9H11N3)2](ClO4)2, the ZnII atom resides on a crystallographic twofold axis and is coordinated by two benzimidazole N [Zn⋯N = 1.993 (4) Å] and two amine N atoms [Zn⋯N = 2.036 (4) Å] in a distorted tetrahedral geometry. The crystal packing is dominated by N—H⋯O interactions involving the perchlorate anions and π–π stacking interactions with an interplanar separation of 3.42 Å. A weak C—H⋯O interaction is also present.
Highlights
In the title compound, [Zn(C9H11N3)2](ClO4)2, the ZnII atom resides on a crystallographic twofold axis and is coordinated by two benzimidazole N [Zn N = 1.993 (4) Å] and two amine N atoms [Zn N = 2.036 (4) Å] in a distorted tetrahedral geometry
We report the synthesis and crystal structure of a new zinc(II)
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.008 Å; disorder in main residue; R factor = 0.066; wR factor = 0.184; data-to-parameter ratio = 12.4. In the title compound, [Zn(C9H11N3)2](ClO4), the ZnII atom resides on a crystallographic twofold axis and is coordinated by two benzimidazole N [Zn N = 1.993 (4) Å] and two amine N atoms [Zn N = 2.036 (4) Å] in a distorted tetrahedral geometry. A weak C—H O interaction is present
Sign-in/Register to view highlights & summary 
Published Version (
Free)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
