Abstract
The molecular structure of the title compound, [Zn(C8H7O2)2(C7H6N2)2]·2C8H8O2, is composed of a mononuclear ZnII complex, which possesses twofold rotation symmetry, and two uncoordinated 4-methylbenzoic acid molecules. The ZnII atom displays a four-coordinate distorted tetrahedral configuration, formed by two carboxylate O atoms of two monodentate 4-methylbenzoate ligands and two N atoms of two benzimidazole molecules. In the crystal structure, complex molecules are linked by the 4-methylbenzoic acid molecules via N—H...O and O—H...O hydrogen bonds, giving rise to the formation of a supramolecular structure.
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