Abstract
In the crystal structure of the title coordination compound, [Ag(NO3)(C14H11N3O2)2], the AgI atom is four-coordinated in a distorted tetrahedral geometry by two O atoms from one nitrate group and two N atoms from two different 1-[(benzoyloxy)methyl]-1H-1,2,3-triazole ligands. In the complex, the two coordinated benzotriazole rings rings are nearly perpendicular, the dihedral angle between their planes being 87.08 (6)°.
Highlights
In the crystal structure of the title coordination compound, [Ag(NO3)(C14H11N3O2)2], the AgI atom is four-coordinated in a distorted tetrahedral geometry by two O atoms from one nitrate group and two N atoms from two different 1-[(benzoyloxy)methyl]-1H-1,2,3-triazole ligands
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: VN2026)
Comment Benzotriazol derivatives have been widely used for constructing complexes with transition metals
Summary
Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.005 A; R factor = 0.032; wR factor = 0.067; data-to-parameter ratio = 12.2. In the crystal structure of the title coordination compound, [Ag(NO3)(C14H11N3O2)2], the AgI atom is four-coordinated in a distorted tetrahedral geometry by two O atoms from one nitrate group and two N atoms from two different 1-[(benzoyloxy)methyl]-1H-1,2,3-triazole ligands. The two coordinated benzotriazole rings rings are nearly perpendicular, the dihedral angle between their planes being 87.08 (6). Related literature For related structures, see: Han et al (2008); Zhou et al (2011). Crystal data [Ag(NO3)(C14H11N3O2)2] Mr = 676.40 Triclinic, P1 a = 9.8815 (5) Ab = 10.6695 (5) Ac = 15.0158 (7) A = 70.405 (2) = 73.323 (2)
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