Abstract
The title compound, (C10H18N)2[GeF6], was obtained hydrothermally from an aqueous solution of GeO2, H3BO3, NiCl2, adamantylammonium chloride, butanol and hydrofluoric acid. The structure consists of discrete bis(1-adamantylammonium) cations lying on crystallographic mirror planes and hexafluoridogermanate anions disordered about sites of 2/m point symmetry. In the latter, the Ge atom lies on the site of 2/m symmetry, one F atom lies on the mirror plane and two further F atoms are included in general positions with 50% site occupancy. The cations and anions lie in layers with N—H⋯F hydrogen bonds formed between them.
Highlights
The structure consists of discrete bis(1-adamantylammonium) cations lying on crystallographic mirror planes and hexafluoridogermanate anions disordered about sites of 2/m point symmetry
The Ge atom lies on the site of 2/m symmetry, one F atom lies on the mirror plane and two further
Symmetry codes: (iv) x, −y−1, z; (v) x+1/2, y−1/2, z
Summary
Institute of Chemistry for Functionalized Materials, College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, People’s National Petroleum Corporation (CNPC), Shiyou Street No 96, Panjin 124010, People’s Republic of China Key indicators: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.006 Å; disorder in main residue; R factor = 0.057; wR factor = 0.144; data-to-parameter ratio = 12.1.
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