Abstract
The asymmetric unit of the title complex, [Ag2(C22H30N4)2](PF6)2, consists of one AgI ion, one 1,4-bis[(3-butylimidazolium-1-yl)methyl]benzene ligand and one discrete hexafluoridophosphate anion. The formula unit is generated by an inversion center. The unique AgI ion is coordinated by two C atoms of two heterocyclic carbene ligands in an essentially linear geometry. In the crystal structure, cations and anions are linked through weak C—H⋯F hydrogen bonds, forming a three-dimensional network.
Highlights
The asymmetric unit of the title complex, [Ag2(C22H30N4)2](PF6)2, consists of one AgI ion, one 1,4-bis[(3-butylimidazolium-1-yl)methyl]benzene ligand and one discrete hexafluoridophosphate anion
The formula unit is generated by an inversion center
The unique AgI ion is coordinated by two C atoms of two heterocyclic carbene ligands in an essentially linear geometry
Summary
R factor = 0.051; wR factor = 0.161; data-to-parameter ratio = 23.1. The asymmetric unit of the title complex, [Ag2(C22H30N4)2](PF6), consists of one AgI ion, one 1,4-bis[(3-butylimidazolium-1-yl)methyl]benzene ligand and one discrete hexafluoridophosphate anion. The formula unit is generated by an inversion center. The unique AgI ion is coordinated by two C atoms of two heterocyclic carbene ligands in an essentially linear geometry. Cations and anions are linked through weak C—H F hydrogen bonds, forming a three-dimensional network
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