Abstract

In the title compound, [Co(C16H14N4O)2](C6H2N3O7)2·3CH3CN, the CoII ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra­hedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by inter­molecular N—H⋯O and N—H⋯N hydrogen bonds. One of the acetonitrile solvent mol­ecules also lies on a twofold rotation axis.

Highlights

  • In the title compound, [Co(C16H14N4O)2](C6H2N3O7)23CH3CN, the CoII ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetrahedral environment by four N atoms from the two bidentate N-heterocycles

  • The crystal structure is stabilized by intermolecular N—H O and N—H N hydrogen bonds

  • The crystal structure is stabilized by intermolecular N—H···O and N—H···N hydrogen bonds

Read more

Summary

Crystal data

Huilu Wu,a* Ruirui Yun,b Xingcai Huang,a Qingyu Suna and Baoliang Qia a School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People’s Republic of China, and bSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People’s

Data collection
For the crystal structures of related dipicrate metal complexes with
Graphite monochromator φ and ω scans
Special details
Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.