Abstract
Two Tc-containing products were isolated from the reaction between CS2and the electron-deficient complex TcCl(dppe)2. The title dithioformate complex, [Tc(S2CH)(dppe)2]·3C6H6, where dppe is 1,2-bis(diphenylphosphino)ethane (C26H24P2), exhibits Tc—P bond lengths ranging from 2.3566 (14) to 2.3884 (14) Å, which are little shorter than normally found. The other product is [TcCl(CS)(dppe)2], and is the first reported Tc–thiocarbonyl complex.
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