Abstract

In the crystal structure of the title compound, [WCl2(NO)(C6H16P2)2]Cl, the seven-coordinated tungsten(II) center displays a distorted penta­gonal–bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4.

Highlights

  • In the crystal structure of the title compound, [WCl2(NO)(C6H16P2)2]Cl, the seven-coordinated tungsten(II) center displays a distorted pentagonal–bipyramidal geometry with trans nitrosyl and chloride ligands

  • The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4

  • Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SU2037)

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Summary

Data collection

The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4

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