Abstract
In the centrosymmetric dimeric title compound, [Cu2(C3H6NS2)4], the CuII atom is five-coordinate in a square-pyramidal environment. The basal coordination positions are occupied by four S atoms from two dimethyldithiocarbamate ligands and the apical coordination position is occupied by an S atom also bonded to the other Cu atom.
Highlights
In the centrosymmetric dimeric title compound, [Cu2(C3H6NS2)4], the CuII atom is five-coordinate in a square-pyramidal environment
The basal coordination positions are occupied by four S atoms from two dimethyldithiocarbamate ligands and the apical coordination position is occupied by an S atom bonded to the other Cu atom
For dialkyldithiocarbamates anions acting as monodentate, bidentate or bridging ligands, see: Engelhardt et al (1988); Fernandez et al (2000); Koh et al (2003)
Summary
Bis(l-N,N-dimethyldithiocarbamatoj3S,S0:S)bis[(N,N-dimethyldithiocarbamato-j2S,S0)copper(II)] Key indicators: single-crystal X-ray study; T = 293 K; mean (N–C) = 0.005 A; R factor = 0.050; wR factor = 0.141; data-to-parameter ratio = 22.8. Crystal data [Cu2(C3H6NS2)4] Mr = 607.91 Monoclinic, C2=c a = 8.068 (3) Ab = 19.446 (7) Ac = 15.108 (6) A = 99.354 (6)
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