Abstract
The title compound, [Cu2(C15H11BrN2O4)2(C3H7NO)2], is derived from the reaction of N′-(5-bromo-2-hydroxy-3-methoxybenzylidene)-2-hydroxybenzohydrazide and copper nitrate in a dimethylformamide solution in the presence of sodium hydroxide. The compound can be regarded as a binuclear centrosymmetric complex. In the crystal, the CuII atom is fivefold surrounded and adopts a distorted square-pyramidal coordination environment. An intramolecular O—H⋯N hydrogen bond stabilizes the molecular conformation.
Highlights
The title compound, [Cu2(C15H11BrN2O4)2(C3H7NO)2], is derived from the reaction of N0 -(5-bromo-2-hydroxy-3-methoxybenzylidene)-2-hydroxybenzohydrazide and copper nitrate in a dimethylformamide solution in the presence of sodium hydroxide
The compound can be regarded as a binuclear centrosymmetric complex
2010QDJ030), the Scientific Research Program funded by Shaanxi Provincial Education Department
Summary
R factor = 0.040; wR factor = 0.123; data-to-parameter ratio = 17.0. The title compound, [Cu2(C15H11BrN2O4)2(C3H7NO)2], is derived from the reaction of N0 -(5-bromo-2-hydroxy-3-methoxybenzylidene)-2-hydroxybenzohydrazide and copper nitrate in a dimethylformamide solution in the presence of sodium hydroxide. The compound can be regarded as a binuclear centrosymmetric complex. In the crystal, the CuII atom is fivefold surrounded and adopts a distorted squarepyramidal coordination environment. An intramolecular O— H N hydrogen bond stabilizes the molecular conformation.
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