Abstract
Abstract The title compound was proposed as a paramagnetic host, and its chelation ability was confirmed by inclusion of a size-matching lanthanum(III) ion. The anti-configuration of the free ligand was changed to the syn configuration in the complex. The antiferromagnetic coupling was enhanced after complexation. In addition to the change of the intramolecular magnetic coupling, a superexchange mechanism is also assumed across the nitroxide–lanthanum(III)–nitroxide structure.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
