Abstract
The ZnII atom in the title compound, [Zn(C6H12NOS2)Cl(C10H8N2)], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN2S2 donor set defines a distorted square-pyramidal coordination geometry. Helical supramolecular chains sustained by O—H⋯S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C—H⋯O, C—H⋯S and C—H⋯Cl interactions.
Highlights
The ZnII atom in the title compound, [Zn(C6H12NOS2)Cl(C10H8N2)], is coordinated by a chelating N-2-hydroxyethylN-isopropyldithiocarbamate ligand, a 2,20 -bipyridine ligand and a Cl atom
Helical supramolecular chains sustained by O—H S hydrogen bonds and propagating along the b axis feature in the crystal packing
A three-dimensional architecture is stabilized by C—
Summary
(Bipyridine-j2N,N0 )chlorido[N-(2hydroxyethyl)-N-isopropyldithiocarbamato-j2S,S0 ]zinc(II) Mohamed Ibrahim Mohamed Tahirb and Edward R. T. School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Malaysia, bDepartment of Chemistry, Universiti Putra Malaysia, 43400 Serdang, Malaysia, and cDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia R factor = 0.031; wR factor = 0.071; data-to-parameter ratio = 18.3.
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