Abstract
The microbiological transformation of 7-oxo- ent-kaur-16-ene by the fungus Gibberella fujikuroi gave fujenoic acid as the main compound, whilst the incubation of 18-hydroxy-7-oxo- ent-kaur-16-ene and 3α,18-dihydroxy-7-oxo- ent-kaur-16-ene afforded the corresponding 6β-hydroxy-derivatives. These facts indicate that the formation of fujenoic acid in this biotransformation should occur via a 7-oxo-6β-hydroxy derivative. In the three biotransformations, an 11β-hydroxylation was also produced, in low yield, indicating that a 7-oxo-group also directs hydroxylation at C-11.
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