Biosynthesized gold nanoparticles supported over TS-1 toward efficient catalyst for epoxidation of styrene

Abstract

Au/TS-1 catalysts prepared by an eco-friendly and economical bioreduction method were used for the liquid phase epoxidation of styrene to styrene oxide (SO) using aqueous hydrogen peroxide (H2O2) as oxidant. The catalysts were characterized by a variety of techniques including FT-IR, DRUV–Vis, UV–Vis, N2 physisorption, XRD, XPS, TG–DTG and TEM. The influence of various parameters (Au loading, calcination, solvents, oxidants, reaction temperature, reaction time and catalyst amount) on the catalytic performance was systematically investigated. The results showed that both the conversion of styrene and selectivity to SO were improved and enhanced when catalyzed by biosynthesized gold nanoparticles (GNPs) supported on TS-1. However, decomposing the Cacumen Platycladi (CP) biomass properly through calcinations can enhance the catalytic performance though it acted as reductant and protective agents during the catalysts preparation. Besides, the optimum catalytic activity and stability of bioreduction Au/TS-1 catalysts were obtained under operational conditions of Au loading of 1.0wt.%, CP extract (10gL−1) as reductant, calcined at 723K for 2h, reaction time of 10h, reaction temperature of 333K, catalyst amount of 500mg, aqueous H2O2 (30wt.%) as oxidant and N,N-dimethylformamide as solvent. Under the optimal condition, styrene conversion of 92.7% and SO selectivity of 90.4% was achieved, which were comparable or even superior to those reported in the literatures. The catalyst was reused five times, without significant decrease in both the styrene conversion and SO selectivity.