Abstract
The labelling pattern arising from incorporation of [1,2-13C2]acetate into astellatol, a novel sesterterpenoid fungal metabolite, supports its biosynthesis via cyclisation and subsequent rearrangement of geranylfarnesyl pyrophosphate, and allows its relationship to a number of other fungal sesterterpenoids to be proposed.
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More From: Journal of the Chemical Society, Perkin Transactions 1
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