Abstract

Biosorption of monovalent ions Na + and K +, by deactivated protonated yeast ( Saccharomyces cerevisiae) at controlled pH, was compared with biosorption of divalent ions Ca 2+ and Mg 2+ to help to understand the underlying binding mechanisms. The adsorption for monovalent ions was accompanied by H + release. Divalent ions were sorbed by proton displacement, and also an additional mode not accompanied by release of H +. The sorption uptake of both monovalent and divalent metal ions increased with pH in the range 3–7 peaking at 6.75. Equilibrium sorption isotherms at pH=6.75 showed that the total maximum biosorptive capacity for metal ions decreased in the following order: Ca>Mg>Na⩾K.

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