Abstract

The purpose of this work is to make use of vegetables that, although widely found in nature, there are few applications. The weeds used here, Cyanthilium cinereum (L.) H. Rob (CCLHR) and Paspalum maritimum (PMT) found in the Amazon region of Belém state of Pará-Brazil, contribute to the problem of water contamination by the removal of the methylene blue dye through the biosorption process, taking advantage of other materials for economic viability and processing. The influences of parameters such as, biosorbent dose, contact time, and initial concentration of dye were examined. The characterizations were realized using SEM to verify the morphology of the material and spectroscopy in the FTIR region. As for the adsorption mechanism, the physical adsorption mechanism prevailed. The time required for the system to reach equilibrium for both biosorbents was from 50 min, following a kinetics described by the pseudo-second order model. The adsorption isotherm data for PMT were better adjusted to the Langmuir model and the biosorption capacity () value was (56.1798 mg/g). CCLHR was better adjusted to the Freundlich model and its maximum biosorption capacity was 76.3359 mg/g. Thus, these weed species are promising for the biosorption of methylene blue dye in effluents.

Highlights

  • The occurrence of weeds in the Amazon Region is considered the most serious biological problem faced by cattle ranchers, as well as their control, one of the highest components of the cost of farms production [1]

  • The biosorption of methylene blue dye (MB) on the adsorbent may be due to the electrostatic attraction between these groups and the cationic dye molecule

  • The adsorption kinetics showed high remove percent and experimental data were most be adjusted by pseudo-second-order model

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Summary

Introduction

The occurrence of weeds in the Amazon Region is considered the most serious biological problem faced by cattle ranchers, as well as their control, one of the highest components of the cost of farms production [1]. It is noteworthy that these plants are undesirable and most of the time they are extracted from nature and discarded or eliminated by chemical processes Another problem in several countries of the world are the industrial processes that generate significant amounts of effluents containing heavy metals and dyes that affect the quality of water one of the resources the most used by living beings. When colorants are present in aquatic environments, color is generally the first impact to be recognized in an effluent because very small amounts of synthetic dyes in water (

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