Abstract

Heavy metal removal from wastewater is a significant research area and recommends sustainable development. The heavy metals cause harmful health effects, increase environmental toxicity. Adsorption is a very effective method for heavy metal removal. A fixed bed for Cu(II) removal using rice hush, an agricultural waste, is reported in this paper. The study was carried out to determine the breakthrough curves with varying operating variables like influent concentration (10–30 mg/L), flow rate (10–40 ml/min), and bed height (4–10 cm) at pH 6. The variation of the process variables like influent concentration, flow rate, and bed height were investigated. The experimental data shows that adsorption capacity increases with the rise of influent concentration. The maximum value of adsorption capacity is 10.93 mg/g at a flow rate of 10 ml/min, bed height 4 cm, and influent concentration 30 mg/L. The applicability of the MLR and ANN modeling has also been successfully carried out. ANN has better predictability than MLR. The findings revealed that rice husk could be used to treat copper-containing industrial effluents.

Highlights

  • Wastewater containing toxic, hazardous heavy metal ions discharged by several industries is a global problem today (Kumar et al, 2019)

  • Physical characterization was made to identify rice husk’s physical properties, and the experiment was done to check the suitability of rice husk to remove Cu(II) ions

  • The maximum adsorption capacity obtained from the Thomas model is 10.93 mg/g at influent concentration 30 mg/L, flow rate 10 ml/min, along with the bed height of 4 cm

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Summary

Introduction

Wastewater containing toxic, hazardous heavy metal ions discharged by several industries is a global problem today (Kumar et al, 2019). This water stream associated with metal ions is mixed with freshwater bodies and makes the new system polluted. These are like Pb(II), Cu(II), Cr(VI), Ni(II), Zn(II), can entered into the functional parts of the living beings through the water bodies and damage these vital parts of the body. Several technologies are present to treat these wastewaters like membrane separation, ion exchange, precipitation, coagulation, adsorption using the activated carbon, and adsorption using bio-sorbent (Aydin et al, 2008). Other processes like membrane separation, ion exchange are not economical, and precipitation, coagulation (Gayathri et al, 2011) are not efficient for industrial-scale treatment.

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