Abstract

Mirabilis jalapa (chandrakantha) leaves were used as a biosorbent for the removal of toxic metals ions cadmium (II), chromium (VI) and lead (II) from water. The physiochemical properties of the developed biosorbent were studied using FTIR. The efficiency of this developed biosorbent was tested using batch experiments under controlled conditions such as a function of pH, contact time, initial metal concentration and the optimization amount of biosorbent. The residual metallic ion concentrations of cadmium (II), chromium (VI) and lead (II) were determined using AAS. The biosorption capacity of Mirabilis jalapa was found to be pH dependant and the percentage removal of cadmium (II), chromium (VI) and lead (II) was increased with increasing adsorbate solution pH and a maximum value was reached at an equilibrium pH = 6 for cadmium (II), pH = 5.5 for chromium (VI) and pH 4.5 for lead (II) respectively. The equilibrium time required for the saturation loading of cadmium (II), chromium (VI) and lead (II) in the biosorbent was found to be about 120 min. The obtained equilibrium biosorption data was fitted to the linear forms of Freundlich isotherms. The results proved the efficiency of Mirabilis jalapa leaves powder as biosorbent for the removal of metal ions and it can be used for the development of an efficient, clean and novel technology for waste water treatment.

Highlights

  • Toxic metal ions mainly cadmium (II), chromium (VI), mercury (II) and lead (II) have a lethal effects on allHow to cite this paper: Shahanaz Begum, S.A., Tharakeswar, Y., Kalyan, Y. and Ramakrishna Naidu, G. (2015) Biosorption of Cd (II), Cr (VI) & Pb (II) from Aqueous Solution Using Mirabilis jalapa as Adsorbent

  • Results demonstrate the important role of selected biosorbent Mirabilis jalapa for the removal of metal ions cadmium (II), chromium (VI) and lead (II) from aqueous samples

  • Adsorption of cadmium (II), chromium (VI) & lead (II) by Mirabilis jalapa was found to be maximum at pH 6 for cadmium (II), pH 5.5 for chromium (VI) & pH 4.5 for lead (II)

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Summary

Introduction

Toxic metal ions mainly cadmium (II), chromium (VI), mercury (II) and lead (II) have a lethal effects on all. Lead is one of the major heavy metal and often found in industrial wastewater and its discharge into the environment poses serious threat due to its toxicity to aquatic and terrestrial lives [9] [10]. Enhanced industrialization such as manufacturing of storage batteries, television tube, printing, paints, pigments, photographic materials, gasoline additives, matches and explosives brings about lead bearing wastewater [11]-[14]. Removal of heavy metals cadmium, chromium and lead from water has been taken up by batch adsorption techniques using Mirabilis jalapa leaves powder as the adsorbent material

Apparatus
Preparation of Bio-Sorbent Material
Batch Adsorption Studies
Adsorption Isotherm Models
Application to Real Water Samples
Results and Discussion
Effect of Contact Time
Effect of Biomass Dosage
Adsorption Isotherms
Conclusions
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