Abstract

Photopolymers have proved to be useful for different holographic applications such as holographic data storage or holographic optical elements. However, most photopolymers have certain undesirable features, such as the toxicity of some of their components or their low environmental compatibility. For this reason, the Holography and Optical Processing Group at the University of Alicante developed a new dry photopolymer with low toxicity and high thickness called biophotopol, which is very adequate for holographic data storage applications. In this paper we describe our recent studies on biophotopol and the main characteristics of this material.

Highlights

  • Photopolymers are light sensitive materials with adequate characteristics for application as recording material in new devices such as optical elements, holographic memories or as holographicMaterials 2012, 5 recording media in research

  • We developed a new photopolymer, biophotopol, with higher environmental compatibility than that of standard acrylamide based photopolymers

  • We observed some properties of biophotopol that could be useful for recording many holograms by multiplexing: the small angular interval of the angular response curve (0.2°)

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Summary

Introduction

Photopolymers are light sensitive materials with adequate characteristics for application as recording material in new devices such as optical elements, holographic memories or as holographicMaterials 2012, 5 recording media in research. Photopolymers are light sensitive materials with adequate characteristics for application as recording material in new devices such as optical elements, holographic memories or as holographic. A specific set of parameters is required of the photopolymers: good energetic sensitivity in order to save energy during the recording process, an adequate spectral sensitivity, and a high resolution to enable fidelity reproduction of the stored information. We describe our line of research on this subject and the main results obtained with biophotopol, a new type of photopolymeric material that the Holography and Optical Processing research team at the University of Alicante is developing [1,2,3]. Photopolymers have a photoinitiator system that absorbs light and generates free radicals that initiate the radical polymerization reaction of one or various monomers. In the case of holographic recording, the basic mechanism of hologram formation involves modulation of the refractive index between polymerized and non-polymerized zones, corresponding to the “bright” and “dark” zones respectively, in the diffraction grating generated due to the interference of the recording beams [4]

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