Abstract
A 4.5-fold difference in catalytic hydrolysis rate constants between stereomer pairs was achieved as a result of the incorporation of bulky substituents into chiral cyclopalladated arylamines used as catalysts for hydrolysis of esters of optically active amino acids. An unexpected inversion of catalyst stereoselectivity depending on the bulkiness of substituents at the palladacycle a-carbon atom was discovered.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
