Abstract
Quantitative extradiol cleavage of a catechol derivative is achieved by exposure of complex 1 to O2 in the presence of AgBF4 and an aromatic nitrogen base. These results provide insight into how the regiochemistry of oxidative cleavage may be controlled by the metal centers of the catechol dioxygenases.
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Schedule a callMore From: Angewandte Chemie International Edition in English
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