Biomass-derived nitrogen doped graphene quantum dots with color-tunable emission for sensing, fluorescence ink and multicolor cell imaging.

Abstract

In this paper, a simple, economical, and green strategy is developed for producing nitrogen doped graphene quantum dots (N-GQDs) with multicolor light emission by hydrothermal treatment of Passiflora edulia Sims. The synthesized N-GQDs exhibit ideal ionic stability, hydrophilicity and anti-photobcleaching properties, and the quantum yield reaches up to about 29%. Because of with the fluorescence quenching effect, the achieved N-GQDs allow to detect Ag+ in a linear range of 10 nM-160 μM, and the limit of detection is calculated to be 1.2 nM according to the S/N of 3. Noteworthy, N-GQDs with blue, green and yellow light emissions are demonstrated via regulating the reaction time and temperature, implying a promising fluorescence adjustability. Furthermore, the N-GQDs-based fluorescent probe exhibits low cytotoxicity and favorable biocompatibility. Depending on the superior properties, our N-GQDs are applied in fluorescent ink and multicolor cell imaging. Eventually, the developed sensor is highly selective and accurate for Ag+ analysis in real water, which demonstrates the promising practical use in environmental determination and/or biomedical engineering.