Abstract
AbstractThis account describes our recent work in the development of new methodologies to prepare rare and biologically potent L‐hexoses and 6‐deoxy‐L‐hexoses, from cheapest D‐glucose, via L‐hexofuranoses and 1,6‐anhydro‐β‐L‐hexopyranoses as key building blocks. Their applications in the syntheses of heparin oligosaccharides, the carbohydrate moiety of bleomycin A2, and L‐acovenose are also summarized here.
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