Biological assisted organic sulfur removal from low rank indigenous coal using airlift bioreactor.

Abstract

Combustion of coal create many harmful gases which effect on human health as well as on environment. The sulfur in coal limits its own use, and bio-desulfurization (BDS) shows enormous development potential and the prospects for the application of coal desulfurization. Present study highlights the bioprocess strategies for reduction of sulfur content from coal before combustion. The bioprocess involved the use of Airlift Bioreactor along with Rhodococcus sp. ATCC55309 as biocatalyst. Different nutritional and operational parameters involved to promote sulfur reduction at maximum level. The parameters were investigated are different carbon source, temperature, pH, Agitation speed, and pulp density. The impact of these parameters shows that sulfur removal can be enhanced though optimized conditions. The amount of total sulfur and organic sulfur present in coal were reduced by 33 ± 1.7% and 71 ± 1.5%, respectively, compared to untreated coal at controlled condition of various parameters are 20% (w/v) pulp density, 30°C, 170rpm, glucose as carbon source and pH 7. Whereas organic sulfur degrades from coal using Rhodococcus sp. ATCC55309 about 0.36mM DBT (Di-benzothiophene) within 8days via 4S-pathway. The maximum conversion of DBT compound into 2-HBP(2-hydroxybiphenyl) by utilizing 30°C, 170rpm, 20 pulp density and glucose as carbon source.