Biogenic sulphide for cyanide recycle and copper recovery in gold–copper ore processing

Abstract

Many complex-ore gold deposits with cyanide-soluble copper minerals such as chalcocite, covellite, bornite, cuprite, malachite and azurite are now being considered for processing. In some cases the ore is not currently being mined largely due to the various issues associated with the cyanide-soluble copper minerals in the ore, which results in low gold recoveries and high cyanide consumption and detoxification costs. Moreover, the presence of copper in tailings supernatant tends to stabilize weak-acid dissociable cyanide in a form toxic to wildlife. In the SART process (sulphidization–acidification–recycle–thickening), the cyanide associated with the copper cyanide complexes is released by NaHS dosing to precipitate copper and convert cyanide to HCN gas under weakly acidic conditions, allowing it to be recycled back to the leach process as free cyanide. Copper is also recovered as a valuable, high-grade (∼70% Cu) Cu 2S by-product. Cyanide recycling allows the leach circuit to be operated at higher cyanide levels, maximizing leach efficiency and minimizing copper deportment to gold electrowinning. The first commercial plant is at Telfer in Western Australia. Biogenically-produced hydrogen sulphide can be used to replace chemical sulphide at significantly lower cost and with the added advantage of lowering the acid demand substantially. While the capital cost of a biogenic SART plant will be higher than a cyanide detoxification plant, this will be more than offset by the revenues generated by copper recovery and the savings realized by cyanide recycle, allowing for a short payback time on the incremental capital. BioteQ is currently working with Columbia Metals Corporation Ltd., Canada, to apply its sulphide generating and precipitation technology in a SART circuit at both of Columbia’s gold projects (La Jojoba and Lluvia de Oro) in Northern Mexico. Processing of ores from both mines has presented challenges resulting from the presence of cyanide-soluble copper. This paper reviews the BioteQ biogenic SART process technology, economics and commercial status as well as environmental and operating outcomes.