Abstract

The demand for fuel oil is ever increasing with the advance of the modern world, whereas worldwide reserves of fossil oils are diminishing at an alarming rate. However, there exist large stockpiles of vegetable oil feedstocks that could be exploited to produce fuel oil, called biodiesel with the aid of biotechnology. Initially, the biodiesel produced from vegetable oil did not attract much attention because of its high cost. However, the recent increase in petroleum prices and the uncertainties of petroleum availability led to the renewal of interest in biodiesel production from such sustainable resources (i.e., vegetable oil feedstocks). This research focuses on the production of biodiesel from plant resources, and further investigates the influences of key process parameters, such as the molar ratio of methanol to oil, catalyst concentration, reaction temperature, reaction period and stirring speed on the biodiesel yield. This investigation is to determine the optimum process parameters for maximum biodiesel yield. The biodiesel was produced from three vegetable oil feedstocks, namely palm, soybean and sunflower oil via a transesterification process. It was observed that all the process parameters significantly influenced the biodiesel yield. The maximum biodiesel yields for palm, sunflower and soybean oil feedstocks were found to be 87.5%, 83.6% and 80.2%, respectively at optimum condition. The results suggest that through proper optimization of the process parameters the biodiesel yields could be maximized. In conclusion, the production of biodiesel from plant resources would be regarded as a sustainable solution to the ever increasing demand of fuel oils.

Highlights

  • Biodiesel is a monoalkyl ester of long chain fatty acids produced from renewable resources such as virgin vegetable oils, waste vegetable oils, animal fats, algae etc. [1,2,3]

  • This research focuses on the production of biodiesel from plant resources, and further investigates the influences of key process parameters, such as the molar ratio of methanol to oil, catalyst concentration, reaction temperature, reaction period and stirring speed on the biodiesel yield

  • The biodiesel was produced from three vegetable oil feedstocks, namely palm, soybean and sunflower oil via a transesterification process

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Summary

Introduction

Biodiesel (known as fatty acid methyl ester) is a monoalkyl ester of long chain fatty acids produced from renewable resources such as virgin vegetable oils, waste vegetable oils, animal fats, algae etc. [1,2,3]. Biodiesel (known as fatty acid methyl ester) is a monoalkyl ester of long chain fatty acids produced from renewable resources such as virgin vegetable oils, waste vegetable oils, animal fats, algae etc. It is an alternative fuel that is used in compression-ignition diesel engine with slight or no modification, and has attracted great attention because of its renewability, better gas emissivity and biodegradability [4]. The biodiesel has been regarded as the potential substitute for petroleum diesel as it offers a number of attractive beneficial properties compared to conventional petroleum diesel [6]. The use of biodiesel maintains a balanced carbon dioxide cycle as it is based on renewable biological materials. Environmentally friendliness due to reduced emissions (carbon monoxide, sulphur, aromatic hydrocarbons and soot particles) during combustion is of another benefit, while it offers non-toxic and complete biodegradabile properties. The production of biodiesel from various sources has been explored by some researchers [7,8,9,10,11,12,13,14]

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