Biodiesel by Co-processing animal fat/vegetable oil mixtures over basic heterogeneous Ca catalyst

Abstract

The use of vegetable oils to produce biodiesel raises several sustainability issues, namely the fuel/food conflict. The high cost of vegetable oils and an expensive homogeneous base catalyzed process encourages the search for alternative raw materials and more efficient production processes. Biodiesel from beef tallow, a non-edible fat, was produced by methanolysis over calcium based heterogeneous catalyst. The catalyst was prepared by calcination of scallop shells at 800 ​°C. To overcome the undesired effect of the tallow acidity (3.9 mg KOH /g fat ), mixtures of tallow and soybean oil (SBO) (0.6 mg KOH /g fat ) were processed and alcohol co-solvents (isopropanol, 1-propanol, and isobutanol) and biodiesel itself, as a solvent, were used to improve the miscibility of the reaction mixture. Processing of neat tallow promotes an important decay of the catalytic activity due to the partial neutralization of the basic catalyst. Co-processing mixtures of tallow/SBO allowed minimizing the acidity effect. Alcohol co-solvents harmed the biodiesel yield due to competitive adsorption of alcohols with methanol on catalyst active sites but protected the catalyst against adsorption of the reaction mixture species. Biodiesel used as a solvent had an almost null effect on the esterification reaction yield, thus showing the absence of mass transfer limitation. Co-processing low-grade fat with vegetable oil seems to be a feasible strategy to process low-grade fats using basic heterogeneous catalysts, thus contributing to improving the sustainability of biodiesel production. • Low-grade animal fat biodiesel was produced by methanolysis over basic catalyst. • Beef tallow was transesterified over Ca heterogeneous catalyst. • Co-processing tallow and soybean oil minimized fat acidity drawback. • Alcohols and FAME solvents were used to improve reaction mixture miscibility. • Solvents prevent catalyst deactivation by avoiding reaction species adsorption.