Biodegradable ether amines for reverse cationic flotation separation of ultrafine quartz from magnetite

Abstract

A considerable amount of ultrafine magnetite as the iron source will end up in the tailing dams since the magnetic separation process markedly drops as the particle size. Cationic reverse flotation could be one of the main alternatives for recovering ultrafine magnetite. As a systematic approach, this study explored the flotation efficiency and interaction mechanisms of two biodegradable ether amines (diamine and monoamine) to separate ultrafine quartz from magnetite (− 20 µm). Several assessments (single and mixed mineral flotation, zeta potential, contact angle, surface tension measurement, turbidity, and Fourier transform infrared) were conducted to explore the efficiency of the process and the interaction mechanisms. Results indicated that ether diamine and monoamine could highly float ultrafine quartz particles (95.9 and 97.7%, respectively) and efficiently separate them from ultrafine magnetite particles. Turbidity assessments highlighted that these cationic collectors could aggregate magnetite particles (potentially hydrophobic coagulation) and enhance their depression. Surface analyses revealed that the collector mainly adsorbed on the quartz particles, while it was essentially a weak interaction on magnetite.