BiOCl Nanosheets with (001), (002), and (003) Dominant Crystal Faces with Excellent Light-Degradation Ability.

Abstract

Gray bismuth chloride nanosheets with a highly enhanced electric field intensity were prepared by a simple and efficient method. Their energy gap is reduced to 2.35 eV. The prepared nanosheets show high photocatalytic activity for the degradation of rhodamine B under visible light. The resulting samples were characterized by X-ray diffractometry, high-resolution scanning electron microscopy, X-ray photoelectron spectroscopy, infrared spectroscopy, UV-vis diffuse reflectance spectroscopy, specific surface area analysis, electrochemical analysis, electron paramagnetic resonance, and UV-vis spectroscopy. The photocatalytic activity of prepared BiOCl was evaluated by the degradation of RhB. The prepared BiOCl sample (0.5 g/L) could completely degrade RhB (10 mg/L) within 10 min, and its visible photocatalytic activity was 80 times that of the original white BiOCl. Superoxide radicals were the main active substance involved in organic degradation.