Biochar sorption of PFOS, PFOA, PFHxS and PFHxA in two soils with contrasting texture

Abstract

The ability to immobilise PFAS in soil may be an essential interim tool while technologies are developed for effective long-term treatment of PFAS contaminated soils. Serial sorption experiments were undertaken using a pine derived biochar produced at 750 °C (P750). All experiments were carried out either in individual mode (solution with one PFAS at 5 μg/L) or mix mode (solution with 5 μg/L of each: PFOS, PFOA, PFHxS and PFHxA), and carried out in 2:1 water to soil solutions. Soils had biochar added in the range 0–5% w/w. Kinetic data were fitted to the pseudo-second order model for both amended soils, with equilibrium times ranging 0.5–96 h for all congeners. PFOS sorption was 11.1 ± 4.5% in the loamy sand compared to 69.8 ± 4.9% in the sandy clay loam. While total sorption was higher in the unamended loamy sand than sandy clay loam for PFHxA, PFOA and PFOS, the effect of biochar amendment for each compound was found to be significantly higher in amended sandy clay loam than in amended loamy sand. Application of biochar reduced the desorbed PFAS fraction of all soils. Soil type and experimental mode played a significant role in influencing desorption. Overall, the relationship between sorbent and congener was demonstrated to be highly impacted by soil type, however the unique physiochemical properties of each PFAS congener greatly influenced its unique equilibrium, sorption and desorption behaviour for each amended soil and mode tested.