Biochar from the co-pyrolysis of Saccharina japonica and goethite as an adsorbent for basic blue 41 removal from aqueous solution

Abstract

The effects of utilizing goethite (5%, 10%, and 20%) in co-pyrolysis with low-lignin macroalgae, Saccharina japonica, on the carbon sequestration potential, magnetic, physicochemical, and dye (basic blue 41, BB41) removal properties of the resulting biochar were investigated. Biochars exhibited more aromaticity, better magnetic properties, and insignificant alterations to their point of zero charges (11.07 ± 0.03 to 10.59 ± 0.01) with goethite increment. Optimum conditions for high organic matter conversion and carbon preservation occurred using 5% goethite. Adsorption experiments showed that BB41 adsorption was highly pH-dependent, equilibrated later (from 12 h to 24 h) after goethite modification, and was best fitted to the pseudo-second-order model (higher R2 and lower SSE values). Langmuir monolayer adsorption capacity for BB41 was the highest amongst carbonaceous adsorbents in the literature [1494 mg/g (pristine); 1216 mg/g (5% goethite)]; initial BB41 concentration of 2000 mg/L at 30 °C and pH 8. The main governing mechanisms involved ion exchanges, hydrogen bonding, π-π interaction and pore-filling. Overall, low goethite amount (5%), co-pyrolyzed with macroalgae, offers an economically and environmentally effective way to produce magnetic biochar with enhanced carbon sequestration potential and superb cationic dye removal performance for environmental remediation applications.