Biochar-advanced thermocatalytic salvaging of the waste disposable mask with the production of hydrogen and mono-aromatic hydrocarbons

Abstract

The salvaging of the waste disposable mask was conducted in this study through catalytic pyrolysis over corn stover derived biochar catalyst combined with the boosted generation of hydrogen and mono-aromatic hydrocarbons for the first time. In the absence of biochar, up to 53 wt% of wax was observed at 550 ºC, whereas at the biochar/mask ratio of 2, around 41 wt% of liquid oil was produced without the formation of wax. The hydrogen content in the gas stream was about 26 vol% at 600 ºC for non-catalytic pyrolysis, which increased to around 55 vol% at the expense of light hydrocarbons such as methane and C2–4 for the catalytic process with the biochar/mask ratio of 3. In resulting liquid oil, the content of mono-aromatics, especially toluene, xylenes, and ethylbenzene was about 55% for catalytic runs, which was far greater than that of 38% from the non-catalytic run. Interestingly, the dyes released from mask pyrolysis could be completely captured/adsorbed by biochar, leading to a much cleaner oil. After 10 cycles of reuse at 600 ºC without regeneration, the biochar still held a good selectivity toward hydrogen and mono-aromatic hydrocarbons. This study exemplified a readily accessible concept and pathway of ‘waste against waste’ targeted to upcycle waste disposable masks over biochar from biomass waste.