Bio-inspired Multifunctional Graphene-Epoxy Anticorrosion Coatings by Low-Defect Engineered Graphene.

Abstract

Although graphene has been regarded as the most ideal anticorrosion filler, to date, some vital problems including poor dispersion, disordered arrangement, structure defects, and galvanic corrosion remain unresolved,, thus blocking its potential application in metal protection. In this work, a bio-inspried multilayered graphene-epoxy composite coating was fabricated through a scalable spraying approach with well-dispersed low-defect engineered graphene as the functional filler. Polydopamine served as an enforcer to improve the dispersity and repair the structure defects of graphene (π-π interaction) and bridged the dense graphene layers and epoxy layers (strong adhesion) for forming "interlock" structures to ensure complete coating systems. Electrochemical tests confirmed that the bio-inspired composite coating showed elevated coating resistance from 4.2 × 106 Ω cm2 for blank coating and 2.5 × 108 Ω cm2 for blending composite coating to 3.0 × 109 Ω cm2. The highly anisotropic graphene layers endowed the bio-inspried coating with highly anisotropic thermal and electrical conductivities, with the in-plane and through-plane thermal conductivities being 0.78 and 0.21 W/mK, respectively. Besides, the good anisotropic conductivities make the bio-inspired coating achieve self-monitoring of structural safety and health. This bio-inspired strategy provides a fascinating method for constructing high-performance graphene composite coatings with functional properties.