Abstract
The binding constants of [Ni(L1)]2+ toward alkaline earth metal ions are relatively small compared with those of free 18-crown-6 and those of [Ni(L1)]2+ toward the alkali metal ions. The reduction potential of the [Ni(L1)](ClO4)2 in the presence of alkaline earth metal ions shifts to the positive direction in the order Mg2+<Ca2+<Sr2+ and Kred/Kox value of this redox process is increased in the order Li+<Na+<K+<Mg2+<Ca2+<Sr2+.
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