Binary vanadium pentoxide carbon-graphene foam composites derived from dark red hibiscus sabdariffa for advanced asymmetric supercapacitor

Abstract

The development of advanced electrode materials derived from biomass for the next generation of energy storage devices, such as supercapacitors with high specific energy and specific power coupled with a good cycle stability, is required to meet the high demand for electric vehicles and portable devices. In this study, sustainable binary vanadium pentoxide carbon-graphene foam composites (V2O5@C-R2HS/GF) were synthesized using a solvothermal method. The X-ray diffraction, Raman and FTIR techniques were used to study the structural properties of the composites (V2O5@C-R2HS/20 mg GF and V2O5@C-R2HS/40 mg GF). The SEM micrographs displayed an accordion-like morphology resulting from the graphene foam-modified V2O5@C-R2HS composite. The V2O5@C-R2HS, V2O5@C-R2HS/20 mg GF and V2O5@C-R2HS/40 mg GF composites were evaluated in a three-electrode configuration using 6 M potassium hydroxide (KOH) as an aqueous electrolyte. Furthermore, a two-electrode device was carried out by fabricating an asymmetric device (V2O5@C-R2HS/GF//AC) where V2O5@C-R2HS/20 mg GF was used as a positive electrode and activated carbon (AC) as a negative electrode at a cell voltage of 1.6 V in 6 M KOH. The V2O5@C-R2HS/GF//AC showed a high specific energy and specific power values of 55 W h kg-1 and 707 W kg-1, respectively, at a specific current of 1 A g-1. The asymmetric device presented a good stability test showing 99% capacity retention up to 10 000 cycles and was confirmed by the floating time up to 150 h with specific energy increasing 23.6% after the first 10 h. This article is part of the theme issue 'Bio-derived and bioinspired sustainable advanced materials for emerging technologies (part 2)'.