Abstract
Synergy was revealed in the action of binary mixtures of heavy metal chelates with N,N,N′,N′-tetrasubstituted p-phenylenediamines in the initiated oxidation of model hydrocarbon ethylbenzene. The value of the synergistic effect (SE), defined as SE = (W add/W mix) − 1, where W mix and W add are the initial rates of oxygen uptake as obtained experimentally and calculated on the assumption of the additive action of the mixture components, respectively, increases with a decrease in the half-wave potential of the one-electron electrochemical oxidation E 1 2/ox of both chelates and tertiary diamines.
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