Abstract
AbstractBinary liquid‐liquid‐equilibria data for several aniline‐paraffin and furfural‐paraffin systems have been taken. These data along with data for other aniline‐hydrocarbon and furfural‐hydrocarbon systems from literature have been correlated using UNIFAC model. The UNIFAC group interaction parameters have been found to have a linear temperature dependence. The CH2 groups in cyclo and non cyclo paraffins require different interaction parameters. It was also found that a scaling of the combinatorial term is necessary for higher molecular weight hydrocarbons.
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