Bimetallic PtNi alloy modified 2D g-C3N4 nanosheets as an efficient cocatalyst for enhancing photocatalytic hydrogen evolution

Abstract

Platinum-based alloy materials as effective cocatalysts in improving the performance of photocatalytic H2 production have raised great interest. Herein, a facile strategy of chemical reduction is established to synthesize bimetallic PtNi nanoparticles on 2D g-C3N4 nanosheets with excellent photocatalytic activity. The addition of PtNi nanoparticles can provide new H+ reduction sites and increase more active sites of the material. The synergistic effect between PtNi alloy nanoparticles and 2D g-C3N4 nanosheets can regulate electronic structure, narrow the band, accelerate charge transfer efficiency and inhabit the recombination of photo-induced electron (e−) and hole pairs (h+), contributing to the improvement of hydrogen evolution activity. The optimal hydrogen evolution rate of Pt0.6Ni0.4/CN shows higher hydrogen evolution rate (9528 μmol·g−1·h−1), which is 13.1 times than that of pure g-C3N4 nanosheets. Besides, a possible mechanism of photocatalytic hydrogen generation has been brought up according to a series of physical and chemical characterization. This work also provides a potential idea of developing cocatalysts integrating metal alloys with 2D g-C3N4 nanosheets for promoting photocatalytic hydrogen evolution.