Abstract
The design and synthesis of efficient electrocatalysts are important for electrochemical conversion technologies. The oxygen evolution reaction (OER) is a key process in such conversions, having applications in water splitting and metal–air batteries. Here, bimetallic carbon nanocubes electrocatalysts are derived from Hofmann-type metal–organic frameworks by carbonization and oxidization (FeNi@OCNC). FeNi@OCNC achieved a current density of 10 mA cm−2 at a low overpotential of 300.4 mV with a very small Tafel slope of 55.4 mV dec−1 in 1 M KOH, and its activity shows 12 h stability. We propose that the coupling effect between Fe, Ni metals is crucial for tuning the electrocatalytic activity, which makes FeNi@OCNC have more oxygen vacancies and higher carbon graphitization degree, thus showing excellent activity. The result may illustrate that bimetallic metal–organic framework-derived carbon nanocubes can be prospective materials for oxygen evolution reaction.
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