Abstract
AbstractA series of pyridine functionalized porous organic polymers (POPs‐Py&PPh3) have been synthesized by polymerizing tris(4‐vinylphenyl)phosphane and 4‐vinylpyridine. The pyridine moieties in the copolymer materials contribute to CO2 adsorption and promote the subsequent conversion of CO2. The POP supported Ru catalyst (Ru/POP3‐Py&PPh3) shows a high catalytic activity (TON up to 710) in the N‐formylation of various primary and secondary amines with CO2/H2, affording the corresponding formamides in good yields (55–95%) under mild reaction conditions. The heterogeneous catalyst can be easily separated from the reaction system and reused for at least eight cycles in the N‐formylation of morpholine.magnified image
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