Bifunctional Co3O4-La2O2CO3@C derived from MOFs for peroxymonosulfate activation to degrade roxarsone and simultaneous removal of released inorganic arsenic from water

Abstract

• MOFs derived difunctional Co 3 O 4 -La 2 O 2 CO 3 @C was successfully fabricated. • ROX was efficiently degraded by Co 3 O 4 -La 2 O 2 CO 3 @C activated PMS. • The generated arsenic was simultaneously adsorbed onto Co 3 O 4 -La 2 O 2 CO 3 @C. • Co 3 O 4 -La 2 O 2 CO 3 @C exhibited superior stability and reusability. • SO 4 − and OH were involved in the oxidation and transformation of ROX. In this study, a novel Co 3 O 4 -La 2 O 2 CO 3 @C composite was fabricated via the calcination of Co-La bimetallic MOFs at 500 °C, and was employed to efficiently activate peroxymonosulfate (PMS) for simultaneous oxidation of roxarsone (ROX) and adsorption of concomitant inorganic arsenic. Approximately 100% of ROX (50 μmol L −1 ) was degraded by PMS (0.5 mmol L −1 ) activated with Co 3 O 4 -La 2 O 2 CO 3 @C (0.2 g L −1 ) at initial pH 6 within 10 min. Meanwhile, the produced inorganic arsenic was almost completely adsorbed within 90 min. The maximum adsorption capacity of As(V) by Co 3 O 4 -La 2 O 2 CO 3 @C was determined to be high up to 275.4 mg g −1 . Co 3 O 4 -La 2 O 2 CO 3 @C also exhibited superior stability. During 6 rounds, the degradation efficiency of ROX and the removal efficiency of the total As maintained almost 100% and more than 97%, respectively. SO 4 − and OH were confirmed to be the reactive oxygen species (ROS) in charge of the degradation of ROX and the conversion of As(III) to As(V). The investigation of the adsorption mechanism revealed that the As species were combined with La species via ligand and anion exchange, resulting in the formation of La-O-As bond. Furthermore, the practical application potential of Co 3 O 4 -La 2 O 2 CO 3 @C in the ROX degradation and the in-situ adsorption of the released arsenic were further evaluated in a continuous flow column reactor. The Co 3 O 4 -La 2 O 2 CO 3 @C composite as catalyst and adsorbent may offer a feasible strategy for the implementation of organoarsenic degradation and produced inorganic arsenic adsorption.