Abstract

In the title compound, the herbicide bifenox, C14H9Cl2NO5, the dihedral angle between the dichlorobenzene and nitro­benzene rings is 78.79 (14)°. In the crystal, C—H⋯O hydrogen bonds give rise to a three-dimensional network structure in which there are both a π–π inter­action [ring centroid separation = 3.6212 (16) Å] and a C—Cl⋯π inter­action [Cl⋯ring centroid = 3.4754 (8) Å]. In addition, short Cl⋯Cl contacts [3.3767 (11) and 3.3946 (11) Å] are present.

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