Abstract
S EAr-type reactions of various heterocycles with ortho-substituted (1′ S, P)-tricarbonyl[(1-chloroethyl)-η 6-benzene]chromium(0) derivatives lead to a family of novel planar chiral bidentate and pseudo-bidentate ligands. Two members of this family (1′ S, P)-2-[1′-tricarbonyl-η 6-((2″- P, P-diphenylphosphino)phenyl)-chromium(0))ethyl] furan and thiophene show high activity and enantioselectivity in the Pd-catalyzed hydrosilylation of styrenes.
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