Abstract
Eighteen complexes of palladium(II) salts and the bidentate chelating ligands cis-1,2-bis(diphenylphosphino)ethylene (vpp). cis-1,2-bis(diphenylarsino)ethylene (vaa), cis-1-diphenylarsino-2-diphenylphosphinoethylene (vasp), and 9,10-bis(diphenylphosphino)phenanthrene (dpph) have been prepared and studied by infrared and electronic spectroscopic techniques. The thiocyanate complexes are formulated Pd(vpp)(SCN) 2 Pd(vaa)(SCN) 2 Pd(vasp)(SCN) 2 and Pd(dpph)(NCS)(SCN), and the possible factors promoting the different types of coordination are discussed.
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