Abstract
1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) with pKa of 26.03 in acetonitrile can be effectively released by photolysis of TBD.HBPh4 salt, which represents a new family of short-wave UV photobase generators. This photobase generator enables the photoinduced living ring-opening polymerization of cyclic esters and the photoinduced cross-linking of various polymeric materials containing the hydroxyl-ester groups.
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